Yeah, you put it in your hot key then click the area to shoot.
But that AoE isn't really practical for kiting or anything. Most people don't use it. Once you hit... 51 you get the Poison Mist which is what you'll be using to AOE kite. That skill is nice if you put on your mouse wheel (if you have it) so that when you're running around you click the wheel then the area ahead or on top of you.
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